Exploring cavities in Type II porous liquids with xenon
نویسندگان
چکیده
The porous topology of Type II Porous Liquids (PLs), prepared using Noria-OEt as an empty molecular host dissolved in 15-crown-5 solvent, is investigated with 129Xe NMR Spectroscopy. Xenon parameters, such chemical shifts and T1 relaxation times, measured PLs solutions at various concentrations, are related to the intrinsic microporous structure material. experimental data interpreted on basis a multiple-site model for xenon atoms within multiple cavities. Diffusion experiments show similar mobility compared pure solvent.
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ژورنال
عنوان ژورنال: Journal of Molecular Liquids
سال: 2023
ISSN: ['0167-7322', '1873-3166']
DOI: https://doi.org/10.1016/j.molliq.2022.121038